Rihanna took to the stage on Music's Biggest Night with a performance of her new song 'FourFiveSeconds.'

Rihanna's new song is in collaboration with fellow Grammy winners Paul McCartney and Kanye West.

For this year's Grammy Awards, Rihanna has been nominated for Best Rap/Sung Collaboration for 'The Monster' with Eminem.

Kanye West, who will also be taking to the stage separately to deliver his solo performance, has been nominated for Best Rap/Sung Collaboration and Best Rap Song for 'Boung 2' with Charlie Wilson.

Other performers of the night include singer and producer Pharrell Williams, who was nominated for a whopping six nominations this year.

Sam Smith, who also received six nominations this year, including the Record of the Year for 'Stay With Me' and Album of the Year for his album titled 'In The Lonely Hour,' will also take to the stage with Mary J. Blige.

Just like Smith, other first time Grammy performers include Ariana Grande, Eric Church, and legendary Australian hard rock band AC/DC.

Another headliner for this year's Grammy performance is Madonna, who is set to heat up the stage once again with her jaw-dropping performance.

Other performances of the night include Chris Martin and Beck, Lang Lang, Herbie Hancock, John Mayer Questlove and Ed Sheeran, Brandy Clark and Dwight Yoakam, Juanes, Sia, Tony Bennett and Lady Gaga, Hozier and Annie Lennox, Jessie J and Tom Jones, Miranda Lambert, Adam Levine and Gwen Stefani, and Usher.

The 57^th annual Grammy Awards took place at the Staples Center in Los Angeles on Feb. 8. A live broadcast is available on CBS Television Network between 8 p.m. to 11.30 p.m. ET.

A video of Rihanna's Grammy performance with Paul McCartney and Kanye West can be seen below: